With the remarkable advent of gravitational-wave astronomy, we have shed light on previously shrouded events: compact binary coalescences. Neutron stars are promising (and confirmed) sources of gravitational radiation and it proves timely to consider the ways in which these stars can be deformed. Gravitational waves provide a unique window through which to examine neutron-star interiors and learn more about the equation of state of ultra-dense nuclear matter. In this work, we study two relevant scenarios forgravitational-wave emission: neutron stars that host (non-axially symmetric) mountains and neutron stars deformed by the tidal field of a binary partner. Although they have yet to be seen with gravitational waves, rotating neutron stars have long been considered potential sources. By considering the observed spin distribution of accreting neutron stars with a phenomenological model for the spin evolution, we find evidence for gravitational radiation in these systems. We study how mountains are modelled in both Newtonian and relativistic gravity and introduce a new scheme to resolve issues with previous approaches to this problem. The crucial component of this scheme is the deforming force that gives the star its non-spherical shape. We find that the force (which is a proxy for the star’s formation history), as well as the equation of state, plays an pivotal role in supporting the mountains. Considering a scenario that has been observed with gravitational waves, we calculate the structure of tidally deformed neutron stars, focusing on the impact of the crust. We find that the effect on the tidal deformability is negligible, but the crust willremain largely intact up until merger.