Studies in nitroxide radical chemistry. - PhDData

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Studies in nitroxide radical chemistry.

The thesis was published by Craig, Robert Lyle, in September 2022, University of Stirling.

Abstract:

First paragraph:
The origin of the term ‘Radical’ can be traced as far back as the early nineteenth century when chemists such as Berzelius, Gay-Lussac and Liebig were tackling the then immense problems presented by the complex structures of organic compounds. Working with hydrogen cyanide, Gay-Lussac and Thenard found that the CN combination could be transferred from compound to compound without its breaking apart into individual carbon and nitrogen atoms. Such a group of two or more atoms that remained in combination while being transferred from one molecule to another was termed a radical from the Latin word for ‘root’. It was believed that organic molecules might be constructed out of a limited number of these ‘roots’.



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